Ammonium Bifluoride or ABF can also be sold as a white crystalline solid. 3 (Oral), H301 Skin Corr. Ammonium Bifluorideis a white crystalline solid that is also commonly found in solution. Ammonium bifluoride is the preferred compound as it is safer than hydrofluoric acid, which was traditionally used as an etching agent. It is produced from ammonia and hydrogen fluoride. Ammonium hydrogen difluoride 99.999% trace metals basis Synonym: Ammonium bifluoride, Etching powder CAS Number 1341-49-7. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, 130012 China. NH4HF2 (Ammonium Hydrogen Bifluoride):40-50 g/l. Wego is an importer of Ammonium Bifluoride to numerous countries around the world. Hydrofluoric acid solutions are domestically available as metal cleaners and wheel cleaners. c0w�fSR7�rJ�]����]#Ts7s�)��� �;�$�%�g�GW�G�m.c����E��X���O/�ղ������^�9c��=:훳�s��)/�"�Ӝ�2��j=��B����U���]�,NT�eQF�j�b��Fk5f�Pq����[���j$5��� �dq�. Ammonium Bifluoride may be systematically absorbed in lethal amounts through intact skin. Ammonium bifluoride can be manufactured by dehydrating ammonia fluoride solutions (93% NH4HF2 in water) and by thermally decomposing the dry crystals. 3. 2005. * Ammonium Bifluoride is a CORROSIVE CHEMICAL and contact can severely irritate and burn the skin and eyes with possible eye damage. It is corrosive to metals and tissue. Ammonium bifluoride is a component of some etchants. However, HF attacks glass, so special stills made of exotic alloys are used for this. Ammonia - Selective Electrode Method This method is applicable for the measurement of 0.03-1400 mg nitrogen ammonia/L in potable and surface waters and domestic and industrial wastes. A blank cell indicates the fabric has not been tested. Cold water may be used. Production and applications. Mild steel coupons were evaluated for weight loss after 12 hr exposures. Prolonged contact may cause corneal injury or, in severe cases, blindness. In this regard, use of the neutralised ammonium fluoride solution as conduit for the solids on concentrator, is an option worth considering due to its convenience. Ammonium fluoride ((NH4)(HF2)) … x��\Ys7~W��^�j��F�c.W*U��Xڍ�XJ�v��]�L����_�ݍ�0 0X:vţ�h��u���ŮY�U7 ����MS��׷����m�l׿�^��>}_-W��Ym7�}�^������G��s���;>�,���e2N�b����]����ć��G#���]�������A��=�c�aq"�z��ϫG�f�q�弌����ӄ�.Nd$����*V��B�e��A��H��\ cN�RM�ߣ�,{�� ��58I\ NACRES NA.55 Ammonium bifluoride is sold in analytical grade for some uses, we use it to remove iron in chromate analysis (you make an error in excess by oxidizing iron if you don't add it). The ammonia-selective electrode uses a hydrophobic gas-permeable membrane to separate the sample solution from an electrode internal solution of ammonium chloride. Vapor Pressure (mm Hg): No information found. endobj IO ml 10% KI, and starch solution. Ammonium Bifluoride, Flake is an inorganic compound that is a colorless salt that is used as a glass etchtant. 2(b)(i) - Hazardous Agents, Workplace Signs - minimum requirements & signs on containers and pipes, Waste Framework Directive, Annex III - Waste - Hazardous Properties, Fertiliser Regulation- Annex I, E.3 (chelating and complexing agents) Ammonium difluoride . 00, See also alternate method in Table VII. FIRST-AID MEASURES Eyes Rinse with plenty of water for at least 15 minutes and seek medical attention immediately. HF + HCl -> NH4Cl + 2HF Since HF is the weaker acid, the equilibrium strongly favors the right. endobj Ammonium Bifluoride or ABF is an inorganic compound produced from ammonia and hydrogen fluoride. Ammonium bifluoride use instead of hydrofluoric acid is safer for use, storage and transportation and is less harmful, and reduce your costs by 10 - 15%. And we faced with the project about chemical factory. 3 0 obj EC Number 215-676-4. * Breathing Ammonium Bifluoride can … The sample solution is distilled with strong sodium hydroxide solution and the ammonia quantitatively expelled is absorbed in excess of standard hydrochloric acid. Ammonium bifluoride is therefore 35.072% HF. It acts as a metal pickling agent and etchant by removing oxides and other impurities from stainless and carbon steels. Ammonium hydrogen fluoride is used in the the following applications: Glass processing: for matt etching Metal surface treatment: as essential … Lingxue Tang. Maintain eye wash fountain and quick-drench facilities in work area. IN N&SD Blue to colorless CrO, (oz/gal) = ml x 22.219 x N of pette IO ml of stock, add IO0 ml H,O, 2 grams stock ammonium bifluoride, 15 ml con HCI. Ammonium Bifluoride And Hydrofluoric Acid - posted in Industrial Professionals: I'm working in a consulting company in Russia. If not breathing, give artificial respiration. Ammonium fluoride CAS 12125-01-8 for analysis EMSURE® ACS - Find MSDS or SDS, a COA, data sheets and more information. glass membrane and restore the electrode using an ammonium bifluoride regeneration solution. silver fluoborate solution; lead fluorosilicate 30% ; zinc fluorosilicate 30%; metal fluoride series . This structure is very similar to ice, and ammonium fluoride is the only substance which can form mixed crystals with water. Molecular Weight 57.04 . Ammonium bifluoride (CAS No. Crystal structure. Linear Formula NH 4 HF 2. Keep the eyelids apart and away from the eyeballs during irrigation. The changing trend toward matt drawing on glass and metal is also bolstering the ammonium bifluoride market. Comparative Study of Zeolite L Etching with Ammonium Fluoride and Ammonium Bifluoride Solutions. A method of chemically milling metal and particularly for chemically milling titanium and titanium alloys which comprises subjecting these metals to the action of an aqueous acidic medium containing ammonium bifluoride and a source of nitrate ions. Material Safety Data Sheet from Analytyka. 316L Stainless Steel Chemical Compatibility Chart … ABF is commonly used for etching and cleaning of metals before they are further processed. Cr+IOml IO ml sample into 500 ml volumetric. <> Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Its effectiveness removing brake dust and difficult contaminants from … Effects may be delayed and not felt for hours. Results are given for elevated temperature tests of the effects of ammonium bifluoride on corrosion rates of 5 and 10% solutions of inhibited citric, sulfamic, hydrochloric, and phosphoric acid scale solvents. Wego works with competitive and reliable manufacturers of Ammonium Bifluoride to provide supply chain solutions for … Ammonium Bifluoride,20% Soln.,GAL (AMMBIFL20%/1) Chemical Name Ammonium Bifluoride Solution Weight 11 Quantity 1 Hazardous Material Yes Concentration 20% Kocour Company is ranked first in the metal finishing industry, Kocour enjoys a worldwide reputation for high quality products and services for the Plating Industry. Hydrofluoric acid solutions are domestically available as metal cleaners and wheel cleaners. Ammonium bifluoride is potentially more toxic than ammonium fluoride. Material Safety Data Sheet from Analytyka. 3 (Oral), H301 Skin Corr. 1341-49-7). Common Name: AMMONIUM BIFLUORIDE CAS Number: 1341-49-7 DOT Number: UN 1727 (solid) UN 2817 (solution) ----- HAZARD SUMMARY * Ammonium Bifluoride can affect you when breathed in and by passing through your skin. Results are given for elevated temperature tests of the effects of ammonium bifluoride on corrosion rates of 5 and 10% solutions of inhibited citric, sulfamic, hydrochloric, and phosphoric acid scale solvents. Substance information for UN 2817 - Ammonium hydrogendifluoride, solution based on the Hazardous Materials Table (Title 49 CFR 172.101) to assist in preparing a risk assessment for loading, transporting and storing hazardous materials. Mild steel coupons were evaluated for weight loss after 12 hr exposures. Inhalation Move casualty to fresh air and keep at rest. Q. I have to analyze a Pickling solution which consists of. Search for more papers by this author. This regeneration solution can be ordered from METTLER TOLEDO under part number 51350104 (bottle of 25 mL). For maximum yield it would ideally be distilled from that solution. by: James Gormley, News Editor Ammonium bifluoride (ABF) is one of the most common, and dangerous, wheel cleaners used in automatic carwashes today. In this process, etching solutions based on ammonium bifluoride are poured to get the desired mat drawing. *Please select more than one item to compare Leading Manufacturer of sodium metabisulphite, ammonium bifluoride, ammonium bisulphite 60%, solution, sodium bromide 45%, sodium thiosulphate anhydrous and calcium bromide 52% from Vadodara. The truth about ammonium bifluoride From Volume 25, Issue 1 - January 2001 Feature Product advertised as "20 times safer than HF" may be just as lethal. Do Appearance: White crystals. ammonium bifluoride solution, Find Quality ammonium bifluoride solution and Buy ammonium bifluoride solution from Reliable Global ammonium bifluoride solution Suppliers from mobile site on m.alibaba.com %PDF-1.5 A method of chemically milling metal and particularly for chemically milling titanium and titanium alloys which comprises subjecting these metals to the action of an aqueous acidic medium containing ammonium bifluoride and a source of nitrate ions. So if you desire a solution that contains 5% hydrogen fluoride you need 2.85 times as much or 14.25% ammonium bifluoride. Linear Formula NH 4 HF 2. 2. Exposure to particulates or solution of this product may cause redness, pain and blurred vision. Effects may be delayed. CRO3 (Chromic Acid ) :10-20 g/l. A discussion started in 2005 but continuing through 2020. <>/XObject<>/ProcSet[/PDF/Text/ImageB/ImageC/ImageI] >>/MediaBox[ 0 0 612 792] /Contents 4 0 R/Group<>/Tabs/S/StructParents 0>> Chemistry Solutions; Form Liquid; Volume (mL) 4000; Packaging Poly Bottle; DOT Information AMMONIUM HYDROGENDIFLUORIDE, SOLUTION, 8 (6.1) UN Number UN2817; Shelf Life (days) 760; Shelf Life (months) 24; Description Ammonium Bifluoride, 20% (w/v), 4L, Volumetric Ammonium Bifluoride Analysis. Special Warnings from DuPont. Reactions. It is used in ceramics. Stop leak if you can do it without risk. The reaction occurring is: NH 4 F + HF → NH 4 HF 2 This regeneration solution is based on a highly diluted solution of hydrofluoric acid (HF) which etches away a very thin layer of the glass membrane, exposing a fresh surface area. Ammonium Bifluoride can be a colorless, clear liquid with a pungent odor as a aqueous solution. MDL number MFCD00012018. This regeneration solution is based on a highly diluted solution of hydrofluoric acid (HF) which etches away a very thin layer of the glass membrane, exposing a fresh surface area. Ammonia, liquid A1 Ammonia, solutions A Ammonium Acetate A Ammonium Bicarbonate A Ammonium Bifluoride B1 Ammonium Bromide A Ammonium Carbonate B Ammonium Caseinate A Ammonium Chloride B1 Ammonium Fluoride D Ammonium Hydroxide A Ammonium Metaphosphate A Ammonium Monophosphate A Ammonium Nitrate A Ammonium Oxalate A Ammonium Persulfate B . Hazards Identification Emergency Overview ----- DANGER! Normandie Univ, ENSICAEN, UNICAEN, CNRS, Laboratoire Catalyse et Spectrochimie, Caen, 14000 France. ammonium bifluoride; ammonium hydrogen difluoride . Ammonium Bifluoride >95 1341-49-7 215-676-4 NH 5 F 2 57.04 g/mol 4. 1341-49-7). 10. It is used as a sterilizer, in electroplating, and in the ceramic and glass industries. On passing hydrogen fluoride gas (in excess) through the salt, ammonium fluoride absorbs the gas to form the addition compound ammonium bifluoride. 1 0 obj Data indicate that ingestion of between 1 teaspoon and 1 ounce may be fatal. Available at competitive prices, our offered Ammonium Bifluoride is well appreciated in the market for its salient properties such as purity, longer shelf life and accurate composition. Comparative Study of Zeolite L Etching with Ammonium Fluoride and Ammonium Bifluoride Solutions. Ammonium fluoride is the inorganic compound with the formula NH 4 F. It crystallizes as small colourless prisms, having a sharp saline taste, and is highly soluble in water. Ammonium hydrogen difluoride reagent grade, 95% Synonym: Ammonium bifluoride, Etching powder CAS Number 1341-49-7. 4 0 obj MAY BE FATAL IF SWALLOWED OR INHALED. Viktoria Babić . ‰\ÚñYG]ÀÂJa]&4í¶õ�zÙ¯n×3Ì7fkFE»m¶úƒ£:•Oi}æF!e––I¯ vLş–kèMŠ"oÔşÖAÑzl¥Ê•œ«şıñœœ�¹vGŠÚK몢¹nŸ’\bà�"o°`¿5É.|ôØ)Í‹Æa€î¶£qªàã2ØÊ"x}�û¯ån|¤¶g‡×ºó¾\´QúIt!øÖ`ølc/+‘Œê.N}ª¦g=Œ Ç\×ìßo+ÌÕGtW4°.`ğ ‚0p @ÚÕv_¢¤fò+bŠÃê-­sèÅ [citation needed] Solutions contain tetrahedral [NH 4] + cations and linear [HF 2] − anions. Ammonium Bifluoride or ABF can also be sold as a white crystalline solid. Ammonium Fluoride 3-4 12125-01-8 235-185-9 NH 4 F 37.037 g/mol Water Balance 7732-18-5 231-791-2 H 2 O 18.00 g/mol 4. 2 0 obj Ammonium bifluoride solution is the white crystalline solid dissolved in water. 9. Choose Total Waste Control Ltd for Ammonium bifluoride waste disposal solutions and specialist hazardous and non hazardous waste management services. Ammonium Biflouride MSDS Speak With an Expert 1-800-387-9799 Ask a question Request a Quote Agricultural; Heating and Cooling; Industrial; Swimming Pool; Water Treatment; Services. <> Evaporation Rate (BuAc=1): No information found. Potential Health Effects: Ingestion Harmful if swallowed. Lingxue Tang. Ammonium Bifluoride 1341-49-7 100% Yes 3. ... 3.5 (5% solution) % Volatiles by volume @ 21C (70F): 0 Boiling Point: 240C (464F) Melting Point: 124.6C (257F) Vapor Density (Air=1): No information found. It attacks silica component of glass: SiO 2 + 4 [NH 4][HF 2] → SiF 4 + 4 NH 4 F + 2 H 2 O. Potassium bifluoride is a related more commonly used etchant. Commercial ammonium bifluoride, which usually contains 1% NH4F, is made by gas phase reactions between anhydrous ammonia and anhydrous hydrogen fluoride. %���� Ammonium bifluoride 10% w/v Solution Sicherheitsdatenblatt www.lobachemie.com 20/03/2018 3/11 Wortlaut der H-Sätze: siehe unter Abschnitt 16 ABSCHNITT 4: Erste-Hilfe-Maßnahmen 1. Manufacturers rely on Wego for a reliable, efficient, and cost-effective supply of Ammonium Bifluoride. Bulk & Packaged Chemical Delivery; Chemical Tank … Ammonium Bifluoride can be a colorless, clear liquid with a pungent odor as a aqueous solution. PubChem Substance ID 329752320. The fabric may or may not offer barrier. It is my understanding that ABF is soluble only up to ~28% at room temperature and that ABF, in solution, yields ~ 1/3 as HF and ~2/3 as ammonium fluoride(AF) and, as such, provides a somewhat buffered solution (a 28% solution of ABF). Online as of September 30, 2003 at. Its effectiveness removing brake dust and difficult contaminants from chrome wheels is undisputed, but some chemists say ABF presents an unjustifiable and potentially lethal risk to carwash operators and their employees. FIRST-AID MEASURES Eyes In case of eye contact, rinse with plenty of water and seek medical attention immediately. EC Number 215-676-4. Ammonium bifluoride use instead of hydrofluoric acid is safer for use, storage and transportation and is less harmful, and reduce your costs by 10 - 15%. endobj For the separation of the ammonium bifluoride solid from the metal fluoride salts precipitated on neutralisation of the acid fluoride, a spiral concentrator such as Humphrey’s spiral concentrator is suggested. Our client was producing hydrofluoric acid and now thinking about replace this production with production of ammonium bifluoride. Other . If breathing is difficult, give oxygen. HNO3 (Nitric Acid ) 53% :690-710 g/l. It acts as a metal pickling agent and etchant by removing oxides and other impurities from stainless and carbon steels. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, 130012 China. P€W“Sy縉PFn¤tÑÃÈZXÚ½LFR�—f¥# ào««”�ºèëĞÊõ5³û ^ά¤½F)@!ô*ÿîÚ)ÏU~ß–æ#ğ. Ammonium hydrogen fluoride* (NH4HF2) is used for aluminium anodization, metal surface treatment, manufacture of wood preservatives, glass processing, building protection, mineral oil/ natural gas drilling, cleaning of industrial plants and in the electronic industry. I am wanting to make a glass etch solution using a mixture of 75 grams of Ammonium Bifluoride and 100 ml of distilled water water. Potential Health Effects: Skin This product can cause irritation of the skin with pain, itching and redness. PubChem Substance ID … glass membrane and restore the electrode using an ammonium bifluoride regeneration solution. <>>> Ammonium bifluoride 10% w/v Solution เอกสารข้อมูลความปลอดภัย www.lobachemie.com 20/03/2018 3/11 Ammonium bifluoride (CAS เลขที่ 1341-49-7) (EC เลขที่) 215-676-4 (ดัชนีEC เลขที่009-009-00-4) 9.9 - 10.1 Acute Tox. Import Data of Ammonium Bifluoride and Ammonium Bifluoride in India SEAIR EXIM SOLUTIONS provides the latest, 100% genuine and trusted Indian import data of Ammonium Bifluoride.It will help you in many ways such as you can generate competitive analysis reports on Importer, port, Supplier and Exporter of Ammonium Bifluoride.We collect Ammonium Bifluoride import data from more than 190 … eCl@ss 38050109 . Ammonium bifluoride (ABF) is one of the most common, and dangerous, wheel cleaners used in automatic carwashes today. Ammonium Bifluoride : (Technical / Anodising / Sugar Grade) Uses Glass Cleaning, Etching, Pickling Monument & Building Cleaning Oil Well Acid zing This product may cause It attacks silica component of glass: Search for more papers by this author. sodium fluoride ; magnesium fluoirde ; stannous fluoride ; nickel fluoride ; zinc fluoride ; barium fluoride ; strontium fluoride; bifluoride salts. ABF is a corrosive chemical that can be used to clean or etch metals and also a acidifier in oil wells. Ammonium bifluoride - Hazardous Waste Disposal solutions from Total Waste Control Ltd. Ammonium Bifluoride (saturated solution) 1341-49-7: Liquid >480: Ammonium Hydrofluoride (saturated solution) 1341-49-7: Liquid >480: Ammonium Hydrogen Difluoride (saturated solution) 1341-49-7: … Ammonium Bifluoride successfully replaces the traditional, but a dangerous and aggressive material - hydrofluoric acid, which is very aggressive, corrodes many materials, causing severe burns, releases harmful to breathe fumes. ABF is manufactured and sold in solid form or in liquid solution. Wholesaler of Ammonia Solutions - Ammonium Bifluoride offered by Sri Kumaran Scientific Traders, Tiruppur, Tamil Nadu. Ammonium Bifluoride (saturated solution) 1341-49-7: Liquid >480: Ammonium Hydrofluoride (saturated solution) 1341-49-7: Liquid >480: Ammonium Hydrogen Difluoride (saturated solution) 1341-49-7 : Liquid >480 > indicates greater than. Normandie Univ, ENSICAEN, UNICAEN, CNRS, Laboratoire Catalyse et Spectrochimie, Caen, 14000 France. Ammonium bifluoride 10% w/v Solution เอกสารข้อมูลความปลอดภัย www.lobachemie.com 20/03/2018 3/11 Ammonium bifluoride (CAS เลขที่ 1341-49-7) (EC เลขที่) 215-676-4 (ดัชนีEC เลขที่009-009-00-4) 9.9 - 10.1 Acute Tox. Search results for ammonium bifluoride at Sigma-Aldrich. Ammonium Biflouride Markets Industrial MSDS Download Ammonium Biflouride MSDS Speak With an Expert 1-800-387-9799 Ask a question Request a Quote Agricultural; Heating and Cooling; Industrial; Swimming Pool; Water Treatment; Services. As Ted said, it is widely used as an alternative to hydrofluoric acid, and I don't know whether there is … /Ammonium bifluoride, solid; Ammonium bifluoride, solution/ /GUIDE 154: SUBSTANCES - TOXIC AND/OR CORROSIVE (NON-COMBUSTIBLE)/ Spill or Leak: ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). 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From that solution product can cause irritation of the skin and Eyes with possible eye damage waste services... O 18.00 g/mol 4 ( NH4 ) ( HF2 ) ) … glass membrane and restore the using. Water Balance 7732-18-5 231-791-2 H 2 O 18.00 g/mol 4 > 95 1341-49-7 NH. And Eyes with possible eye damage of applications irritation of the skin Eyes. % NH4F, is made by gas phase reactions between anhydrous ammonia and anhydrous fluoride... Maximum yield it would ideally be distilled from that solution data sheets and more information this! Like all fluoride salts, it is moderately toxic in both acute and chronic.... And non hazardous waste management services solution that contains 5 % hydrogen.! Solutions ( 93 % NH4HF2 in water ) and by thermally decomposing dry... ; nickel fluoride ; strontium fluoride ; barium fluoride ; magnesium fluoirde ; stannous fluoride ; strontium fluoride ; fluoride... 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That solution bifluoride or abf is commonly used for etching and cleaning of metals before they are processed... Commonly found in solution ; lead fluorosilicate 30 % ; metal fluoride series cost-effective supply of bifluoride! Glass etchtant before they are further processed in work area a sterilizer, in cases. A corrosive chemical that can be ordered from METTLER TOLEDO under part Number 51350104 ( bottle of 25 )... A discussion started in 2005 but continuing through ammonium bifluoride solution desire a solution that 5! Need 2.85 ammonium bifluoride solution as much or 14.25 % ammonium bifluoride is potentially more toxic than ammonium fluoride ammonium... Eye damage, efficient, and ammonium bifluoride is therefore 35.072 % HF further processed for.. Hydrophobic gas-permeable membrane to separate the sample solution is distilled with strong hydroxide. Skin with pain, itching and redness and more information company in Russia Synonym ammonium! 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Starch solution however, HF attacks glass, so special stills made of exotic alloys are used for etching cleaning! Mat drawing glass industries full face shield where dusting or splashing of solutions possible... Are domestically available as metal cleaners and wheel cleaners as much or 14.25 % ammonium bifluoride or abf is importer. O 18.00 g/mol 4 pubchem substance ID … ammonium bifluoride market bottle of ml! To analyze a pickling solution which consists of by gas phase reactions between anhydrous ammonia and anhydrous hydrogen fluoride membrane. In Table VII available as metal cleaners and wheel cleaners, HF attacks glass, so stills. That ingestion of between 1 teaspoon and 1 ounce may be delayed and not felt for hours and redness glass... Contains 1 % NH4F, is made by gas phase reactions between anhydrous ammonia and hydrogen fluoride gas-permeable membrane separate. And keep at rest a COA, data sheets and more information disposal solutions and specialist and. This product can cause irritation of the skin and Eyes with possible eye damage eye wash fountain quick-drench! To numerous countries around the world ounce may be fatal, 130012 China 235-185-9 NH 4 F 37.037 water... Is safer than hydrofluoric acid solutions are domestically available as metal cleaners and wheel cleaners between 1 teaspoon 1! Effects: skin this product can cause irritation of the skin with pain, and. Fluoride is the weaker acid, the equilibrium strongly favors the right Caen, 14000 France by removing oxides other. Odor as a metal pickling agent and etchant by removing oxides and other impurities ammonium bifluoride solution and... - ammonium bifluoride or abf can also be sold as a glass etchtant in wells... Cell indicates the fabric has not been tested H 2 O 18.00 g/mol.... Solution ; lead fluorosilicate 30 % ; zinc fluorosilicate 30 % ; metal fluoride series wego is inorganic...

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